General
Chemical Engineering
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Introduction to Chemical Engineering
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History of Chemical Engineering
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Thermodynamics
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Transport Phenomena
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Reaction Engineering
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Process Control and Instrumentation
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Legacy Course
Laws of Thermodynamics
Thermodynamics is a branch of physics that deals with the study of energy and work of a system. It has three laws that form the foundation of the field:
The first law of thermodynamics, also known as the law of energy conservationThe professional care, preservation, and restoration of archaeological materials and sites, often requiring scientific expertise., states that energy cannot be created or destroyed, only converted from one form to another. This means that the total energy in a closed system must remain constant. In other words, the energy that is put into a system must be equal to the energy that is taken out of the system. This law is also known as the law of conservation of energy.
The second law of thermodynamics, also known as the law of entropyAn indicator of the physical disorder of a system., states that heat cannot be completely converted into work in a closed system. This means that not all of the energy in a system can be used to do work. Some of the energy will always be wasted as heat. The second law of thermodynamics also states that the entropy of a closed system will always increase over time. Entropy is a measure of the disorder or randomness of a system.
The third law of thermodynamics, also known as the law of absolute zero, states that as the temperature of a system approaches absolute zero (0 K or -273.15°C), the entropy of the system approaches a minimum. This means that at absolute zero, a system will have the least amount of disorder or randomness possible. It is important to note that it is impossible to reach absolute zero, as it is the theoretical lowest limit of temperature.
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